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Find the latent heat of the fusion of ice with the help of the experiment.

OR

Describe experiments to determine the heat of fusion and latent heat of fusion of ice by sketching a temperature-time graph on heating ice.

Difficulty: Hard

Experiment:

Take a beaker and place it over a stand. Put small pieces of ice in the beaker and suspend a thermometer in the beaker to measure the temperature. Place a burner under the beaker. The ice will start melting. The temperature of the mixture containing ice and water will not increase above 0°C until all the ice melts. Note the time which the ice takes to melt completely into the water at 0°C

Continue heating the water at 0°C in the beaker. Its temperature will begin to increase. Note the time which the water in the beaker takes to reach its boiling point at 100°C from 0°C.

 

Draw a temperature-time graph as shown in figure 8.11. Calculate the latent heat of fusion of ice from the data as follows:


Let, the mass of ice = m


Finding the time from the graph:


Time taken by ice to melt completely at 0°C =$ t_{f} = t_{2-} t_{1} $ =  3.6 min.
Time taken by water to heat from 0°C to 100°C =$ t_{0} = t_{3-} t_{2}$ =  4.6 min.
Specific heat of water c = $4200 J〖kg〗^{-1} K^{-1}$.
Increase in the temperature of water = $\triangle T$ = 100°C =100 K
Heat required by water from 0°C to 100°C =$ \triangle Q$ = $ mc \triangle T$
=$m \times 4200 Jkg^{-1} K^{-1} \times 100K$
= $m\times 420 000 Jkg^{-1}$
= $m \times 4.2 \times 10^{5} Jkg^{-1}$


Heat $ \triangle Q$ is supplied to water in time $t_{0}$ to raise its temperature from 0°C to 100°C. Hence, the rate of absorbing heat by the water in the beaker is given by:


Rate of absorbing heat =  $ \triangle Q/(t_{0})$
∴ Heat absorbed in time  $t_{f} = Δ Q = (ΔQ× t_{f})/(t_{0})$ =$\frac{\triangle Q \times ( t_{f})}{(t_{0})}$ 
Since, $\triangle Q_{f}$ = $ m \times H_{f}$                  (from eq. 8.7)


Putting the values, we get:


$m \times H_{f}$  =  $m \times 4.2\times 10^{} Jkg^{-1}\times ( t_{f})/(t_{0})$
or, $H_{f}$= $\frac{4.2 \times 10^{5} Jkg^{-1} \times ( t_{f})}{(t_{0})}$ 
The values of $t_{f}$ and$ t_{0}$ can be found from the graph. Put the values in the above equation to get
$H_{f}$ = $4.2 \times 10^{5} Jkg^{-1} \times ( 3.6min)/(4.6min )$
= $3.29 \times 10^{5}  Jkg^{-1}$

     
The latent heat of fusion of ice found by the above experiment is $3.29 \times 10^{5}  Jkg^{-1}$   while its actual value is $3.36 \times 10^{5} Jkg^{-1}$.

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